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NFPA 704 Classification

1. Special notice

Code
Description
ACIDAcid
ALKAlkaline
BIOBiological Hazard
CORCorrosive
CRYOCryogenic
OXOxidizer
POIPoisonous
RADRadioactive
SASimple Asphyxiant
-W-Reacts With Water
Blank

 

2. Instability/Reactivity

Code
Description
0Stable
1Unstable If Heated
2Violent Chemical Change
3Stock/Heat May Detonate
4May Detonate

 

3. Health

Code
Description
0Normal Material
1Slightly Hazardous
2Hazardous
3Extreme Danger
4Deadly

 

4. Flammability

Code
Description
0Will Not Burn
1Above 200°F
2Between 100°F and 200°F
3Below 100°F
4Below 73°F

 

Globally Harmonized System (GHS) for Classification and Labelling of Chemicals


1. GHS Pictograms

Code
Description
SGH01Explosives
SGH02Flammable Liquids
SGH03Oxidizing Liquids
SGH04Compressed Gases
SGH05Corrosive
SGH06Acute Toxicity
SGH07Toxic, Irration
SGH08Aspiration Hazard
SGH09Hazardous to the Aquatic Environment


2. GHS Hazard Statements

H200Unstable explosive
H201Explosive; mass explosion hazard
H202Explosive; severe projection hazard
H203Explosive; fire, blast or projection hazard
H204Fire or projection hazard
H205May mass explode in fire
H206Fire, blast projection hazard; increased risk of explosion if desensitized agent is reduced
H207Fire or projection hazard; increased risk of explosion if desensitized agent is reduced
H208Fire hazard; increased risk of explosion if desensitized agent is reduced
H220Extremely flammable gas
H221Flammable gas
H222Extremely flammable aerosol
H223Flammable aerosol
H224Extremely flammable liquid and vapour
H225Highly flammable liquid and vapour
H226Flammable liquid and vapour
H227Combustible liquid
H228Flammable solid
H229Pressurized container: may burst if heated
H230May react explosively even in the absence of air
H231May react explosively even in the absence of air at elevated pressure and/or temperature
H232May ignite spontaneously if exposed to air
H240Heating may cause an explosion
H241Heating may cause a fire or explosion
H242Heating may cause a fire
H250Catches fire spontaneously if exposed to air
H251Self-heating; may catch fire
H252Self-heating in large quantities; may catch fire
H260In contact with water releases flammable gases which may ignite spontaneously
H261In contact with water releases flammable gases
H270May cause or intensify fire; oxidizer
H271May cause fire or explosion; strong oxidizer
H272May intensify fire; oxidizer
H280Contains gas under pressure; may explode if heated
H281Contains refrigerated gas; may cause cryogenic burns or injury
H290May be corrosive to metals
H300Fatal if swallowed
H300 + H310Fatal if swallowed or in contact with skin
H300 + H310 + H330Fatal if swallowed, in contact with skin or if inhaled
H300 + H330Fatal if swallowed or if inhaled
H301Toxic if swallowed
H301 + H311Toxic if swallowed or in contact with skin
H301 + H311 + H331Toxic if swallowed, in contact with skin or if inhaled
H301 + H331Toxic if swallowed or if inhaled
H302Harmful if swallowed
H302 + H312Harmful if swallowed or in contact with skin
H302 + H312 + H332Harmful if swallowed, in contact with skin or if inhaled
H302 + H332Harmful if swallowed or if inhaled
H303May be harmful if swallowed
H303 + H313May be harmful if swallowed or in contact with skin
H303 + H313 + H333May be harmful if swallowed, in contact with skin or if inhaled
H303 + H333May be harmful if swallowed or if inhaled
H304 May be fatal if swallowed and enters airways
H305May be harmful if swallowed and enters airways
H310Fatal in contact with skin
H310 + H330Fatal in contact with skin or if inhaled
H311Toxic in contact with skin
H311 + H331Toxic in contact with skin or if inhaled
H312Harmful in contact with skin
H312 + H332Harmful in contact with skin or if inhaled
H313May be harmful in contact with skin
H313 + H333May be harmful in contact with skin or if inhaled
H314Causes severe skin burns and eye damage
H315Causes skin irritation
H315 + H320Causes skin and eye irritation
H316Causes mild skin irritation
H317May cause an allergic skin reaction
H318Causes serious eye damage
H319Causes serious eye irritation
H320Causes eye irritation
H330Fatal if inhaled
H331Toxic if inhaled
H332Harmful if inhaled
H333May be harmful if inhaled
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335May cause respiratory irritation
H336May cause drowsiness or dizziness
H340May cause genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H341Suspected of causing genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H350May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H351Suspected of causing cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H360May damage fertility or the unborn child (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H361Suspected of damaging fertility or the unborn child (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H362May cause harm to breast-fed children
H370Causes damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H371May cause damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H372Causes damage to organs (or state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H373May cause damage to organs (or state all organs affected, if known)through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard)
H400Very toxic to aquatic life
H401Toxic to aquatic life
H402Harmful to aquatic life
H410Very toxic to aquatic life with long lasting effects
H411Toxic to aquatic life with long lasting effects
H412Harmful to aquatic life with long lasting effects
H413May cause long lasting harmful effects to aquatic life
H420Harms public health and the environment by destroying ozone in the upper atmosphere

 

3. GHS Precautionary Statements

P101If medical advice is needed, have container or label at hand
P102Keeout of reach of children
P103Read label before use
P201Obtain sinstructions before use
P202Do not handle until all safety have been read and understood
P210Keeaway from heat, hot surfaces, soflames and other ignition sources. No smoking.
P211Do not son an oflame or other igntion source
P212Avoid heating under confinement or reduction of the desensitized agent
P220Keeaway from clothing and other combustible materials
P222Do not allow contact with air
P223Do not allow contact with water
P230Keewetted with …
P231Handle and store contents under inert gas/…
P231 + P232Handle and store contents under inert gas/… from moisture
P232from moisture
P233Keecontainer tightly closed
P234Keeonly in original packaging
P235Keecool
P240Ground and bond container and receiving equipment
P241Use ex[electrical/ventilating/lighting/…] equipment
P242Use only non-stools
P243Take action to static discharges
P244Keevalves and fittings free from oil and grease
P250Do not subject to grinding/shock/friction/…
P251Do not or burn, even after use
P260Do not breathe dust/fume/gas/mist/vapours/spray
P261Avoid breathing dust/fume/gas/mist/vapours/spray
P262Do not get in eyes, on skin, or on clothing
P263Avoid contact during and while nursing
P264Wash … thoroughly after handling
P270Do not eat, drink or smoke when using this product
P271Use only outdoors or in a well-ventilated area
P272Contaminated work clothing should not be allowed out of the workplace
P273Avoid release to the environment
P280Wear gloves/clothing/eye protection
P282Wear cold insulating gloves and either face shield or eye protection
P283Wear fire resistant or flame retardant clothing
P284[In case of inadequate ventilation] wear resprotection
P301IF SWALLOWED:
P301 + P310IF SWALLOWED: Immediately call a CENTER/doctor/…
P301 + P312IF SWALLOWED: Call a CENTER/doctor/… if you feel unwell
P301 + P330 + P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P302IF ON SKIN:
P302 + P334IF ON SKIN: Immerse in cool water [or wrain wet bandages]
P302 + P335 + P334IF ON SKIN: Brush off loose from skin. Immerse in cool water [or wrain wet bandages]
P302 + P352IF ON SKIN: Wash with of water…
P303IF ON SKIN (or hair):
P303 + P361 + P353IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]
P304IF INHALED: IF INHALED: Call a CENTER/doctor/… if you feel unwell
P304 + P340IF INHALED: Remove to fresh air and keecomfortable for breathing
P305IF IN EYES:
P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if and easy to do. Continue rinsing
P306IF ON CLOTHING:
P306 + P360IF ON CLOTHING: Rinse immediately contaminated clothing and skin with of water before removing clothes
P308IF exor concerned:
P308 + P311IF exor concerned: Call a CENTER/doctor/…
P308 + P313IF exor concerned: Get medical advice/attention
P310Immediately call a CENTER/doctor/…
P311Call a CENTER/doctor/…
P312Call a CENTER/doctor/… if you feel unwell
P313Get medical advice/attention
P314Get medical advice/attention if you feel unwell
P315Get immediate medical advice/attention
P320Streatment is urgent (see … on this label)
P321Streatment (see … on this label)
P330Rinse mouth
P331Do NOT induce vomiting
P332If skin irritation occurs:
P332 + P313If skin irritation occurs: Get medical advice/attention
P333If skin irritation or a rash occurs:
P333 + P313If skin irritation or rash occurs: Get medical advice/attention
P334Immerse in cool water [or wrain wet bandages]
P335Brush off loose from skin
P336Thaw frosted with lukewarm water. Do not rub affected areas
P336 + P315Thaw frosted with lukewarm water. Do not rub affected area. Get immediate medical advice/attention
P337If eye irritation persists:
P337 + P313If eye irritation Get medical advice/attention
P338Remove contact lenses, if and easy to do. Continue rinsing
P340Remove to fresh air and keecomfortable for breathing
P342If exressymptoms:
P342 + P311If exressymptoms:
P351Rinse cautiously with water for several minutes
P352Wash with of water/…
P353Rinse skin with water [or shower]
P360Rinse immediately contaminated clothing and skin with of water before removing clothes
P361Take off immediately all contaminated clothing
P361 + P364Take off immediately all contaminated clothing and wash it before reuse
P362Take off contaminated clothing
P362 + P364Take off contaminated clothing and wash it before reuse
P363Wash contaminated clothing before reuse
P364And wash it before reuse
P370In case of fire:
P370 + P372 + P380 + P373In case of fire: Exrisk. Evacuate area. DO NOT fight fire when fire reaches explosives
P370 + P376In case of fire: Stoleak if safe to do so
P370 + P378In case of fire: Use … to extinguish
P370 + P380 + P375In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion
P370 + P380 + P375 [+ P378][In case of fire: Evacuate area. Fight fire remotely due to the risk of ex[Use…to extinguish]
P371In case of major fire and large quantities:
P371 + P380 + P375In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion
P372Exrisk
P373DO NOT fight fire when fire reaches explosives
P375Fight fire remotely due to the risk of explosion
P376Stoleak if safe to do so
P377Leaking gas fire: Do not extinguish, unless leak can be stosafely
P378Use … to extinguish
P380Evacuate area
P381In case of leakage, eliminate all ignition sources
P390Absorb sto material damage
P391Collect spillage
P401Store in accordance with…
P402Store in a dry place
P402 + P404Store in a dry Store in a closed container
P403Store in a well-ventilated place
P403 + P233Store in a well-ventilated Keecontainer tightly closed
P403 + P235Store in a well-ventilated Keecool
P404Store in a closed container
P405Store locked up
P406Store in a corrosion resistant/… container with a resistant inner liner
P407Maintain air gabetween stacks or pallets
P410from sunlight
P410 + P403from sunlight. Store in a well-ventilated place
P410 + P412from sunlight. Do not exto temexceeding 50 °C/122 °F
P411Store at temnot exceeding … °C/… °F
P412Do not exto temexceeding 50 °C/122 °F
P413Store bulk masses greater than … kg/…lbs at temnot exceeding …°C/…°F
P420Store separately
P501Disof contents/container to …
P502Refer to manufacturer or sufor information on recovery or recycling

 

4. Country Specific Hazard Statements

EUH001Explosive when dry
EUH006Explosive with or without contact with air
EUH014Reacts violently with water
EUH018In use may form flammable/explosive vapour-air mixture
EUH019May form explosive peroxides
EUH029Contact with water liberates toxic gas
EUH031Contact with acids liberates toxic gas
EUH032Contact with acids liberates very toxic gas
EUH044Risk of explosion if heated under confinement
EUH066Repeated exposure may cause skin dryness or cracking
EUH070Toxic by eye contact
EUH071Corrosive to the respiratory tract
EUH201Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
EUH201AWarning! Contains lead.
EUH202Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
EUH203Contains chromium (VI). May produce an allergic reaction.
EUH204Contains isocyanates. May produce an allergic reaction.
EUH205Contains epoxy constituents. May produce an allergic reaction.
EUH206Warning! Do not use together with other products. May release dangerous gases (chlorine).
EUH207Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer. Comply with the safety instructions.
EUH208Contains (name of sensitising substance). May produce an allergic reaction.
EUH209Can become highly flammable in use.
EUH209ACan become flammable in use.
EUH210Safety data sheet available on request.
EUH401To avoid risks to human health and the environment, comply with the instructions for use.